Cool.
I have no idea if it will effect the "thump", but the switch will last beyond our lifetimes I would guess, after doing this "mod".
And, if it is the capacitor charging that causes the thump, perhaps a "stand-by" mode could be created, whereby the main caps remain powered, and therefore charged, and the front switch brings the regulated power on-line. It would require a rear-mounted "main power" switch (which could be over-rated, and maybe even be one of those integrated noise-filters with attached fuse, used on computers).
I have some components set up like this- the phono preamp has exactly zero switches (always under power, if plugged in), and my CD transport has a rear main power switch, to keep some components "warm" and ready to use. I think my preamp is the same as well.
My "ultimate" design would be to have the transformers and rectification external, bringing only DC up to the main cabinet. Further capacitor reserve and voltage regulation can happen there, to reduce loss over the cable length from the A/C external power supply. Then use the rear main/front sub-system power switching scheme.
But again, I don't know anything...