So you are probably talking about the 10uF bypass caps used with the input tube cathode resistors in the ultra-linear pre-amp designs. This is a RC network to filter the DC supply to the tube. I have heard of even larger caps, up to 250uF for power amps, to bypass the output tube cathode resistors. These caps are not in the signal path, so they are not critical to the sound as long as they are robust enough to handle the applied voltages.