I would be cautious Glen. Modern electrolytic capacitor voltage ratings really should not be exceeded but sometimes you can cheat a bit. I would form them to your measured rail voltage but again you need to be careful. Jerry had one vent on him and it sounded like it created a bit of a mess. Optimally you want to have a cap like this working at 80% or less of its rated voltage. Are you using the 2k ohm resistor in series with your power source to measure leakage current?