I had this quandry/dilemma/head scratcher/question about some Orange Drops I used when re-building a Heathkit tube integrated. I used Orange Drops to replace all of the, as the assembly manual called them, "tubular capacitors". The manual stressed that the capacitors be installed exactly as shown which referred to an end of them marked with a "bar". Being as how my understanding was that film capacitors are non-polarized, I installed the new ones without heed to a possible polarity difference. What I ended up with was the amp worked splendidly on all inputs except MAG PHONO which had a hum. Two people checked it out but neither could identify what was causing the hum. I also asked why the original capacitors were marked but again, neither knew. Maybe this stuff is before their time.
I formulated what I thought was stupid idea that maybe all the new components were picking up noise where the old ones were not. In doing a considerable amount of online reading, I learned that one lead of a capacitor is the outside layer. I thought perhaps that if I was able to identify which was which, I could mark the outside layer leads and re-install them as per the manual's direction. I posted this question on DIY Audio and got a few responses - some were over my head. But this suggestion was given for determining which capacitor lead was which:
To find the outer foil connect the cap to an amp input. Hold the cap in your fingers. Note the level of hum. Turn the cap around. Try again. Loudest hum means the outer foil is connected to the amp input. You can use a scope instead of an amp if you have one.
Since I have no scope, this is excellent information. I received this tidbit of knowledge only recently and have yet to put it to use. It will be soon though as I think this might be the answer.
EDIT: this comment preceded the above:
Normally the outer foil should connect to the lower impedance node - could be ground if it is a decoupling or filter cap, or the anode if it is a coupling cap.
If, as seems to be the case here, the cap can pick up significant hum then it is not only necessary to get it the right way round but also in the right position - distance from nearby AC conductors matters. Keep it well away from heater wiring, for example. This sort of thing was routine in the 1950s, but modern audio enthusiast have forgotten these old skills.